» Structure Of Organic Compounds
» Isomerism Of Organic Compounds
» Halogenated Derivatives
» Carboxylic Acids
The simple function combinations are equivalent with the substances containing one characteristic group of an organic function. The simplest formula of this combination is R-X, in which R is the rest of hydrocarbon (the radical) and X is the functional group. When several identical functional groups are found in the molecule, the respective combination has a multiple function (it is poly functional).
The organic halogenated combinations can be taken as deriving from a hydrocarbon by the substitution of one or more hydrogen atoms with halogen atoms. The number of halogenated derivates is known to be very big. The most used are, in decreasing order, the chloride derivates, the bromides and the iodides. The fluoride derivates also have a technical importance, especially in the refrigerating industry and some organic polymers.
The denomination of the halogenated derivates is formed from the name of the hydrocarbon (deriving from) preceded with a prefix indicating the number and the nature of the halogen atoms. For example, the chloride derivates of methane are called: CH3Cl mono chloromethane, CH2Cl2 dichloromethane, CHCl3 trichloromethane and CCl4 tetra chloromethane. Also, in the case of molecules with more than one carbon atoms you must indicate, at the same time, the carbon atoms which the halogens are connected to. Hence, for example, if at the dichloroethane the two chlorine atoms are bound to a carbon atom CHCl2-CH3, the chloride derivate is called 1,1-dichloroethane; if the two chlorine atoms are connected to two carbon atoms CH2Cl-CH2Cl, the chloride derivate is called 1,2-dichloroethane.
According to the above demonstration, the denomination of the halogenated derivates is:
Because of the formal look alike between the halogenated derivates of the hydrocarbons and the inorganic salts of the halogenated hydracids (the metal is being replaced by an organic radical), an older nomenclature, only sometimes used, expresses the halogenated combinations as the organic radicals halogen. For example, the mono chloromethane CH3Cl is also named methyl chloride; the chloroethane C2H5Cl is also called ethyl chloride and the chloropropane C3H7Cl is also named propyl chloride.
The number of the halogenated derivates isomers is very big, taking into account the rich number of possibilities of substituting the hydrogen atoms, as well as the position the halogen occupies in the molecule. From methane and ethane (in which all the hydrogen atoms in the molecule are identical), you obtain only one mono halogenated derivate. On the other hand, at propane, there are two mono halogenated derivates:
CH2Cl-CH2-CH3 (1-chloropropane or n-propyl chloride)
CH3-CHCl-CH3 (2-chloropropane or isopropyl chloride)
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